Material
Safety Data Sheet
| Material
Name: Koester VAP 1® - 2000, part B |
ID:
KAC-001 |
| *
* * Section 1 - Chemical Product and Company identification
* * * |
| |
| Product
Use: Epoxy resin |
|
| Manufacturer
Information |
|
| Koester
America Corp. |
Phone:
1 -757-425-1206 |
|
2585 Aviator Drive
|
|
| Virginia
Beach, VA 23453 |
Emergency
# INFOTREC: 1-800-535-5053 |
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|
General Comments NOTE:
Emergency telephone numbers are to be used only in the event
of chemical emergencies involving a spill, leak, fire, exposure,
or accident involving chemicals. All non-emergency questions
should be directed to customer service. |
| *
* * Section 2 - Composition / Information on Ingredients *
* * |
| |
|
|
| CAS
# |
Component |
Percent |
| 2855-13-2 |
Isophorone diamine |
50-61.5 |
| 98-54-4 |
p-tert-Butylphenol |
10-15 |
| 25068-38-6 |
Bisphenol
A - (epichlorohydrin, reaction product) |
6.0-8.5 |
| 15520-10-2 |
2-Methylpentamethylenediamine |
1-5 |
| 100-51-6 |
Benzyl
alcohol |
<1 |
| |
|
|
Component
Information/Information on Non-Hazardous Components
This product is considered hazardous under 29 CFR 1910.1200
(Hazard Communication). |
| *
* * Section 3 - Hazards Identification * * * |
Emergency
Overview
This product is a combustible, colorless liquid epoxy resin
with an amine-like odor, used as half of a two part system.
This product is harmful by inhalation and if it is swallowed.
Contact with this material will cause burns to the skin, eyes
and mucous membranes. This product may cause sensitization by
skin contact. |
Potential
Health Effects: Eyes
This product causes eye burns. Contact with the eyes may cause
moderate to severe eye injury. Eye contact may result in cornea!
injury. Symptoms may include discomfort or pain, excess blinking
and tear production, with marked redness and swelling of the
conjunctiva. |
Potential
Health Effects: Skin
This product is severely irritating to the skin and may cause
burns. This product may cause an allergic skin reaction. |
Potential
Health Effects: Ingestion
This product may be harmful if it is swallowed. This product
may produce corrosive damage to the gastrointestinal tract if
it is swallowed. |
Potential
Health Effects: Inhalation
This product is harmful by inhalation. Excessive inhalation
of vapors from this product may cause nausea, vomiting and diarrhea.
Inhalation of vapors or mists of the product may be irritating
to the respiratory system. |
| HMIS
Ratings: Health: 3 Fire: 2 Reactivity: 1 |
| Hazard Scale: 0 = Minimal
1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic
hazard |
| *
* * Section 4 - First Aid Measures * * * |
First
Aid: Eyes
Immediately flush eyes with water for at least 15 minutes, while
holding eyelids open. Seek medical attention at once. |
First
Aid: Skin
For skin contact flush with large amounts of water. Wash affected
area with mild soap and water. If irritation persists, get medical
attention. Immediately take off all contaminated clothing. Wash
contaminated clothing before reuse. |
First
Aid: Ingestlon
If the material is swallowed, get immediate medical attention
or advice - Do not induce vomiting. |
First
Aid: Inhalation
If inhaled, immediately remove the affected person to fresh
air. Seek medical attention if symptoms develop or persist.
|
| *
* * Section 5 - Fire Fighting Measures * * * |
| |
|
| Flash
Point: >194°F (>90° C) |
Method
Used: N/A |
| Upper
Flammable Limit (UFL): N/A |
Lower
Flammable Limit (LFL): N/A |
| Auto
Ignition: N/A |
Flammabillty
Classification: Combustible |
| Rate
of Burning: N/A |
|
General
Fire Hazards
This product is combustible at high temperatures. |
Hazardous
Combustion Products
Carbon monoxide, carbon dioxide, various hydrocarbon fragments
as well as thick smoke. |
Extinguishing
Media
Water spray, dry chemical, carbon dioxide. Use water to cool
fire-exposed containers and to protect personnel. |
Fire
Fighting Equipment/Instructions
Firefighters should wear full protective clothing including
self contained breathing apparatus. |
| |
|
| NFPA
Ratings: Health: 3 Fire: 2 Reactivity: 1 |
| Hazard Scale:
0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe |
|
* * * Section 6 - Accidental Release
Measures * * * |
Containment
Procedures
Do not allow contact with skin, eyes or mucous membranes. Avoid
inhalation of vapor from the spilled material. Contain the discharged
material. |
Clean-Up
Procedures
Absorb spill with inert material. Shovel material into appropriate
container for disposal. Ventilate the contaminated area. Wear
appropriate protective equipment and clothing during clean-up. |
Evacuation
Procedures
Isolate area. Keep unnecessary personnel away. |
Special
Procedures
Remove soiled clothing and launder before reuse. Follow all
Local, State, Federal and Provincial regulations for disposal.
Do not allow product to enter sewer or waterways. |
| *
* * Section 7 - Handling and Storage * * * |
Handling
Procedures
Do not get this material in your eyes, on your skin, or on your
clothing. Do not inhale vapors or mists of this product. Do
not reuse the empty container. Use this product with adequate
ventilation. Wash thoroughly after handling. Keep this product
from heat, sparks, or open flame. Do not eat, drink or smoke
when using this product. Do not mix this product with fluids
which contain NITRITES/NITRATES. NITROSAMINE may be formed. |
Storage
Procedures
Store only in the original container. Store tightly closed and
in an upright position in a cool, dry, well-ventilated area.
|
| *
* * Section
8 - Exposure Controls / Personal Protection *
* * |
| Exposure
Guidelines |
A: General
Product Information
No information available for the product. Attempts should be
made to eliminate all contact with skin and eyes, and to limit
inhalation exposure. |
B: Component
Exposure Limits
ACGIH, OSHA, and NIOSH have not developed exposure limits for
any of this product's components. |
Engineering
Controls
Use general ventilation and use local exhaust, where possible,
in confined or enclosed spaces. |
| PERSONAL
PROTECTIVE EQUIPMENT |
Personal
Protective Equipment: Eyes/Face
Wear chemical goggles; face shield (if splashing is possible). |
Personal
Protective Equipment: Skin
Use impervious gloves. Work clothing sufficient to prevent all
skin contact should be worn, such as coveralls and long sleeves. |
Personal
Protective Equipment: Respiratory
If ventilation is not sufficient to effectively prevent buildup
of vapors, appropriate NIOSH approved respiratory protection
must be provided. |
Personal
Protective Equipment: General
Eyewash fountains and emergency showers are required. |
| *
* * Section 9 - Physical & Chemical Properties * * * |
| |
|
| Appearance:
Colorless |
Odor:
Amine-like |
| Physical
State: Liquid |
pH Vapor
Pressure: Not available |
| Vapor
Pressure: Not available |
Vapor
Density: Not available |
| Boiling
Point: Not available |
Melting
Point: Not available |
| Solubility
(H20): Not available |
Specific
Gravity: 1.02 g/cm (Density) |
| Viscosity:
800 mPas @ 73.4° F (23° C) |
VOC:
<10 g/L |
| *
* * Section 10 - Chemical Stability & Reactivity information
* * * |
Chemical
Stability
Stable under normal conditions. |
Chemical
Stability: Conditions to Avoid
Keep away from heat, ignition sources and incompatible materials.
Do not mix this product with nitrates or other nitrosating agents
because a carcinogenic nitrosamine may be formed. |
Incompatibility
This product may react with oxidizers, acids, bases, amines,
phenols, mercaptans, isocyanates and anhydrides. |
Hazardous
Decomposition
Upon decomposition, this product emits carbon monoxide, carbon
dioxide, chlorine, aldehydes and phenol. |
Hazardous
Polymerization
Will not occur. |
| *
* * Section 11 - Toxicoloqical Information * * * |
| Acute
and Chronic Toxicity |
A: General
Product Information
Product contains Bisphenol A which may cause allergic skin sensitization
reactions in sensitive individuals. |
| B: Component
Analysis - LD50/LC50 |
p-tert-Butylphenol
(98-54-4)
Oral LD50 Rat: 3250 uL/kg
Dermal LD50 Rabbit: 2520 uL/kg |
| |
Bisphenol
A - (epichlorohydrin), reaction product (25068-38-6)
SL6475000:Phenol, 4,4""-isopropylidenedi-, polymer with 1-chloro-2,3-epoxypropane
(10/1/97)
Oral LD50 Rat: 11400 mg/kg
Oral LD50 Mouse : 15600 mg/kg |
| |
Benzyl
alcohol (100-51 -6)
Oral LD50 Rat: 1230 mg/kg
Oral LD50 Mouse : 1360 mg/kg
Dermal LD50 Rabbit: 2 gm/kg |
| |
| Carcinogenicity |
A: General
Product Information
No information available for the product. |
B: Component
Carcinogeniclty
None of this product's components are listed by ACGIH, IARC,
OSHA, NIOSH, or NTP. |
| *
* * Section 12 - Ecological Information * * * |
Ecotoxicity
No information available for the product. |
Environmental
Fate
Slightly harmful to aquatic systems. Keep liquid from entering
sewers and natural waterways. |
| *
* * Section 13 - Disposal Considerations * * * |
| US EPA
Waste Number & Descriptions |
A: General
Product Information
Wastes must be tested using methods described in 40 CFR Part
261 to determine if it meets applicable definitions of hazardous
wastes. As shipped, this product would be considered a D002
(corrosive) waste. |
B: Component
Waste Numbers
No EPA Waste Numbers are applicable for this product's components. |
Disposal
Instructions
Purchaser is advised to review regulations referenced for applicability
as determined by purchaser's use of the product. All wastes
must be handled in accordance with local, state and federal
regulations. |
| *
* * Section 14 - Transportation Information * * * |
|
US DOT
Information
Shipping Name: Polyamines, liquid, corrosive, n.o.s.
(Contains: Isophorone diamine , p-tert-Butylphenol, 2- Methylpentamethylenediamine)
Hazard Class: 8
UN/NA #:UN2735
Packing Group: II
Required Label(s): CORROSIVE
Additional Info.: This product contains a Marine Pollutant
which must be added to the shipping information if the product
is shipped in bulk packaging (containers >119 gallons or 450
liters) via surface transportation and all packages shipped
via water transportation.
|
| |
International
Transportation Regulations
International Air Transportation Association (IATA):
Shipping Name: Polyamines, liquid, corrosive, n.o.s.
(Isophorondiamine, p-Tert butyl phenol, Bisphenol A - (epichlorohydrin),
reaction product)
Hazard Class: 8
UN/NA #: UN3267
Packing Group: II
Required Label(s): Corrosive |
| ***
Section 15-Regulatory Information *** |
| US Federal
Regulations |
A: General
Product Information
All components are on the U.S. EPA TSCA Inventory List. |
B: Component
Analysis
None of this products components are listed under SARA Section
302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65),
or CERCLA (40 CFR 302.4). |
| |
| Acute
Health: Yes Chronic Health: No Fire: Yes
Pressure: No Reactive: Yes |
| State
Regulations |
A: General
Product Information
Other state regulations may apply. Check individual state requirements. |
B: Component
Analysis - State
The followinq components appear on one or more of the followina
state hazardous substances lists: |
| Component |
CAS
# |
CA |
FL |
MA |
MN |
NJ |
PA |
| Isophorone
diamine |
2855-13-2 |
No |
No |
No |
No |
Yes |
No |
| Benzyl
Alcohol |
100-51-6 |
No |
Yes |
Yes |
Yes |
No |
Yes |
|
Component
Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous
Products Act Ingredient Disclosure List:
| Component |
CAS
# |
Minimum
Concentration |
| Isophorone
diamine |
2855-13-2 |
1%;
English Item 899; French Item 1048 |
| p-tert-butylphenol |
98-54-4 |
1%;
English Item 258; French Item 366 |
|
| Additional
Regulatory Information |
A: General
Product Information
No additional information available |
| B:
Component Analysis - InventoryComponent Analysis - Inventory |
| Component |
CAS
# |
TSCA |
DSL |
EINECS |
| Isophorone
diamine |
2855-13-2 |
Yes |
Yes |
Yes |
| p-tert-butylphenol |
98-54-4 |
Yes |
Yes |
Yes |
| Bisphenol
A - (epichlorohydrin), reaction product |
25068-38-6 |
Yes |
Yes |
No |
| 2-Methylpentamethylenediamine |
15520-10-2 |
Yes |
Yes |
Yes |
| Benzyl
alcohol |
100-51-6 |
Yes |
Yes |
Yes |
|
| ***
Section 16 - Other Information * * * |
Other
Information
Reasonable care has been taken in the preparation of this information,
but the manufacturer makes no warranty of merchantability or
any other warranty, expressed or implied, with respect to this
information. The manufacturer makes no representations and assumes
no liability for any direct, incidental or consequential damages
resulting from its use. |
MSDS
History
New MSDS Date: 02/19/2001
Revision Update: 08/29/2001 |
Key/Legend
ACGIH = American Conference of Governmental Industrial Hygienists.
BOD = Biological Oxygen Demand. CERCLA = Comprehensive Environmental
Response, Compensation and Liability Act. CFR = Code of Federal
Regulations. EINECS = European Inventory of Existing Commercial
Chemical Substances. EPA = Environmental Protection Agency.
HEPA = High Efficiency Particulate Air. HMIS = Hazardous Material
Information System. IARC = International Agency for Research
on Cancer. NFPA = National Fire Protection Association. NIOSH
= National Institute of Occupational Safety and Health. NJTSR
= New Jersey Trade Secret Registry. NTP = National Toxicology
Program. OSHA = Occupational Safety and Health Administration.
NA = Not available or Not Applicable. SARA = Superfund Amendments
and Reauthorization Act. ThOD = Theoretical Oxygen Demand. TLV
= Threshold Limit Value. TSCA = Toxic Substance Control Act.
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